Unlocking more sustainable futures with green chemistry

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Unlocking more sustainable futures with green chemistry is an article that was researched and written by Isabel Williams, a former Masters Student at Oxford University’s Department of Biology.
But achieving SDGs by generalising what is proposed remains to be seen.

Using chemistry to help reach sustainability goals is becoming an increasingly attractive research area. From solving global plastic pollution to improving the performance of rechargeable batteries found in electric cars, ‘green chemistry’ is a truly promising topic.

This article was researched and written by Isabel Williams, a former Masters Student at Oxford University’s Department of Biology.

Tackling the plastic pollution problem

 

A heap of mixed plastic waste floating on the ocean.

Synthetic plastics do not break down easily, causing them to be a major pollutant in natural environments. Image credit: mbala mbala merlin/ Getty Images.

We are all too aware of the global plastic problem. Plastics are unsustainably produced, made, and disposed of, with the material found in the ocean, in landfills, on beaches, and even in the Antarctic. Researchers at the University of Oxford are applying innovative techniques to help tackle this problem.

But why is plastic such a problematic material? To find out why and to begin to tackle these problems, one needs to look at the material’s chemistry.

Plastics are made from synthetic ‘polymers’. Polymers are made from small molecular building blocks, called ‘monomers’, forming a large molecule resembling beads on a string. In plastics, these monomers are usually derived from non-renewable sources such as petrochemicals, making the production of plastic polymers highly unsustainable since they rely on fossil fuels. Additionally, due to the strong bonds between their monomers, synthetic polymers can persist and pollute the environment for hundreds of years before breaking down.

The solution: replacing plastics with ‘greener’ polymers

 

Dr Matilde Concilio (left) and Dr Gregory Sulley (right). Photo credit: Dr Gregory Sulley

Whilst efforts to reduce plastic usage and increase recycling can go a long way, it is unlikely that we can eliminate plastics entirely, particularly for uses that have food safety or human hygiene concerns. Many everyday items contain plastic polymers – including shopping bags, paint, electric car batteries, clothing, teabags, and takeaway coffee cups. But if we are not able to completely eliminate plastics, can they be replaced with a greener, more sustainable version?

Researchers at the University of Oxford’s Department of Chemistry are utilising a green chemistry approach to tackle plastic pollution. The aim? To phase out existing polymers and plastics and replace them with greener, more sustainable alternatives.

One avenue being explored is the production of polymers from renewable, bio-derived materials, rather than petrochemicals. Dr Matilde Concilio, a Postdoctoral Research Associate in Professor Charlotte Williams’ laboratory, works on making bio-derived polymers from commercially available resources. By using chemicals already commercialised, safety-checked, and approved, the hope is that any products or processes developed in this way will be swiftly accepted and adopted by industry. With bio-derived plastics accounting for only 1.5% of global plastic production in 2021, there is enormous potential for these materials to upscale and ultimately replace their less-sustainable competitors.

I’m convinced that polymers are the future, but only if you do it in a sustainable way.

 

Dr Matilde Concilio, Department of Chemistry

Dr Concilio’s bio-derived polymers are not only made from renewable sources but are also more sustainable from a processing standpoint. Usually, monomers need to be purified many times to achieve a high-quality final product. This is both energetically costly and expensive.

‘So, to make it more sustainable, what I’m trying to do is use monomers that don’t need to be purified’ Dr Concilio explains. This way, less energy, time, and money are spent on the polymerisation process.

Key to the development and uptake of these new polymers is ensuring that their material properties are as good as, if not better than, current petrochemically-derived options. This is essential if these new materials are to be adopted at scale within plastics industries.

Ultimately, what we want to do is phase out [the current plastics], so that our plastics, which we’re quite heavily reliant on as a society, come from renewable sources.

 

Dr Gregory Sulley, Department of Chemistry

‘One of the main targets for us is to try and property-match to the incumbent materials,’ says Dr Gregory Sulley, another Postdoctoral Research Associate in Professor Charlotte Williams’ laboratory. ‘Ultimately, what we want to do is phase out [the current plastics], so that our plastics, which we are quite heavily reliant on as a society, come from renewable sources.’

With continued work and collaboration, hopefully, sustainable plastics will go on to replace their more unsustainable alternatives, making plastic pollution a problem of the past. With any luck, the sight of plastic in our landfills, oceans, and beaches will soon be a distant memory.

Tailor-made polymers for energy storage solutions:

Similar green chemistry approaches are being applied to solve problems in energy storage. For instance, rechargeable batteries require their components to be in contact with one another to function. However, this is complicated by the fact that some of the components change volume as the battery is charged and discharged. With these batteries used in electric cars, solar panels, and wind turbines, overcoming this problem is a huge priority to help reach Net Zero emission targets.

So, how do you solve this problem? Enter polymers.

 

Dr Georgina Gregory. Photo credit: Royal Society.

Dr Georgina Gregory, a Royal Society Dorothy Hodgkin Fellow, also works on bio-derived polymers. Dr Gregory was formerly a Postdoctoral Research Associate in Professor Charlotte Williams’ laboratory, like Dr Concilio and Dr Sulley, but now has progressed to lead a lab group of her own. What unites these three researchers, other than their shared history with the ‘Polymer Magician’ Professor Williams, is their ability to produce bespoke polymers designed for a specific application.

This application-driven design is integral to Dr Gregory’s work to improve the design of polymers so that they can overcome the current limitations of rechargeable batteries.

‘The polymer, in some respects, comes in as a way of holding it all together’ Dr Gregory explains. This means the polymer needs to be:

  1. Adhesive: to stick everything together in the battery;
  2. Slightly flexible: to accommodate the changes in volume;
  3. Ionically conductive: the polymer needs to allow ions (electrically charged atoms) to flow through the battery.

With these three properties in mind, the researchers set out to precisely design a polymer for use in batteries. By specifically selecting building blocks possessing these properties, and utilising their ability to tightly control the polymerisation process, they were able to tailor the product to the problem.

The story continues, read more of it on University of Oxford News & Events

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What is urban mining – and why do we need to do more of it?

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What is urban mining – and why do we need to do more of it? And why do we need to do more of it? is reviewed in this article.

 

The image above is (Credit: Unsplash)

This article is brought to you thanks to the collaboration of The European Sting with the World Economic Forum.

Author: Charlotte Edmond, Senior Writer, Forum Agenda


 

  • The vast majority of us own a smartphone – and inside each one are metals and minerals that could help the environment.
  • This is an example of urban mining -.the practice of extracting materials from waste – which is a key part of the circular economy.
  • Other materials that could be saved from landfill and incineration include waste from demolition and construction.

 

The number of smartphones in use hit 6.6 billion in 2022. That means the vast majority of the world now owns one. And inside each of those phones is a pinch of multiple different metals and minerals, some of which are rarer and harder and more damaging to extract than others.

But each of these phones also has a limited life – how many people have an old device sitting unused in a drawer somewhere? One piece of research estimates that there are around 7 million unused phones in Switzerland alone, with $10 million worth of embedded gold in them.

It is exactly issues like these that make it so important we get an urban mining system up and running in a sustainable and cost-effective way.

 

What is urban mining?

Urban mining is the idea of extracting valuable materials from waste, much of which would otherwise go to landfill or incineration. This can include common metals and plastics as well as rarer but valuable elements.

Urban mining allows us to salvage materials of which there is a finite supply, and limits the environmental impact of their disposal. Crucially, it also avoids extraction of additional materials, which damages ecosystems and can cause pollution, among other things.

It forms a key part of the circular economy, which promotes a more sustainable use of resources by keeping them in use for as long as possible.

Discover

What is the World Economic Forum doing about the circular economy?

The World Economic Forum’s Platform for Shaping the Future of Consumption is seeking to promote responsible consumption models, which are equitable, enable societal well-being and protect the planet. A key part of the initiative is focused on innovative reuse models.

The waste we can recycle

Electronic waste (e-waste) like phones is a prime candidate for urban mining, where products cannot otherwise be repaired.

There are a growing number of companies which offer to buy back and resell unwanted devices, as well as a wave of repair cafes emerging. But these devices are still not routinely considered an economically viable secondary source of materials like gold, silver, copper, lithium, or cobalt.

Once you factor in the environmental costs of extracting these materials, however, the scales tip in favour of urban mining, research suggests. Many of the participants in the Swiss phone study mentioned above said they would be willing to sell their old phone for less than $5. The market value of the metals within them is under $2, but when you factor in the external costs of extraction the cost of the materials is around $18.

Another strong use case is for waste materials from demolition or construction. Around 850 million tons of construction and demolition waste were created by Europe alone in 2020 – more than a third of all waste generated in the region.

Steel, copper and aluminium are commonly found in demolition waste. And there are also ways which cement – a notoriously polluting material in its production – can be reused and recycled. Some processes even manage to capture and store carbon in the new product. Aggregates and bitumen from worn-out roads can also be recycled into new ones.

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‘No end in sight’ to rising greenhouse gases

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‘No end in sight’ to rising greenhouse gases – UN weather agency declared based on the WMO latest report.

A World Meteorological Organization (WMO) headquarters is pictured before a news conference to launch state of global climate report at the United Nations in Geneva, Switzerland, May 18, 2022. REUTERS/Denis Balibouse/File Photo Acquire Licensing Rights

 

GENEVA, Nov 15 (Reuters) – The concentration of greenhouse gases in the atmosphere reached a record high last year, the World Meteorological Organization (WMO) said on Wednesday, warning there was “no end in sight” to the trend.

The warning comes weeks before world leaders are due to gather in Dubai for the annual U.N. climate conference COP28, which will see governments push for greater climate action, including a possible phase-out of fossil fuels before 2050.

In 2022, global average concentrations of carbon dioxide were a full 50% above the pre-industrial era for the first time, the U.N. weather agency said.

“Despite decades of warnings from the scientific community, thousands of pages of reports and dozens of climate conferences, we are still heading in the wrong direction,” said WMO Secretary-General Petteri Taalas.

Taalas said higher concentrations of greenhouse gases would be accompanied by more extreme weather events, including intense heat and rainfall, ice melt, higher sea levels, as well as ocean heat and acidification.

“About half of the planet has been facing an increase of flooding events, and one third of the planet has been facing an increase of drought events,” Taalas said. “And this negative trend will continue until 2060s.”

“We must reduce the consumption of fossil fuels as a matter of urgency,” he said.

Methane concentrations in the atmosphere also increased, and levels of nitrous oxide, another greenhouse gas, saw the highest year-on-year increase on record between 2021 and 2022, WMO said.

Greenhouse gases are responsible for warming the planet and triggering extreme weather events. Unlike emissions which can be cut, much of the carbon dioxide emitted decades ago remains in the atmosphere and activates slow processes like the increase of the sea level.

“It takes thousands of years to remove carbon from the system once it’s emitted into the atmosphere,” Taalas said.

A separate UN report published on Tuesday said that governments were making insufficient progress in slashing greenhouse gas emissions to avert the worst impacts of global warming.

Reporting by Gabrielle Tétrault-Farber; Editing by Christina Fincher and Bernadette Baum

Our Standards: The Thomson Reuters Trust Principles.

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The battle against air pollution

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The battle against air pollution, per the author of a Jordan Times article, is an overwhelming issue that transcends borders and requires urgent attention.

The above-featured image is for illustration and is credit to INHABITAT

Nov 10, 2023

 

Air pollution within the closest layer of the atmosphere where life exists, which is called the biosphere, has experienced a global environmental crisis that affects the health and well-being of people and other living beings around the world. It’s an issue that transcends borders and requires urgent attention.

The combustion of fossil fuels of industries and the built environment is a major source of air pollution. Factories and houses burning fossil fuels for construction, heating and cooling release pollutants such as sulfur, carbon and nitrogen oxides, among others. Encouraging industries and buildings in general to adopt energy-efficient and clean renewable energy practices can cut emissions while saving cost, maintenance and investment.

The transportation sector powered by gasoline and diesel, contributes significantly to air pollution. An average vehicle passenger emits around 4.6 metric tons of carbon dioxide each year depending on the vehicle’s fuel, car fuel economy, and the distance covered. Short-term exposure to high levels of certain air pollutants, such as carbon monoxide or lead, can lead to acute neurological symptoms, including confusion, dizziness and seizures.

Agriculture is another source emitting gases, such as ammonia, nitrous oxide and methane, primarily from ploughing, fertilisers, land changes and livestock. Land-use changes, such as deforestation, can affect air quality and reduce the planet’s capacity to absorb and store carbon dioxide.

Power plants that rely on coal, oil, or natural gas to produce electricity release pollutants into the air, including greenhouse gases like carbon dioxide and methane. Coal combustion emissions can exceed one kilogramme of carbon dioxide for each Kilo Watt hours of electricity generated.

As glaciers melt due to rising global temperatures, various gases are released into the atmosphere, contributing to climate change. Two prominent gases are methane, and carbon dioxide which occurs as ice containing ancient air pockets melts, intensifying the greenhouse effect further warming the planet.

Global warming has intensified wildfires, releasing gases into the atmosphere as trees and vegetation burn. Fine particulate matter is also released, impacting air quality, human health and exacerbating climate change, air pollution, and associated health issues and biodiversity damage, emphasising the urgent need for effective wildfire management and climate mitigation strategies.

Air pollution can lead to respiratory diseases such as asthma, bronchitis, and lung infections. Long-term exposure to pollutants is linked to heart diseases and increased mortality rates. Children exposed to air pollution may experience reduced lung development, leading to lifelong health problems. Exposure to fine particulate matter, ozone, and nitrogen dioxide can lead to eye irritation, redness, and dry eyes. This can result in discomfort, itching, and a feeling of grittiness in the eyes. Airborne allergens like pollen and mold spores can become more concentrated in polluted air, increasing the risk of allergy. Prolonged exposure to air pollution may affect visual acuity. In Jordan, you can visit MOE site to monitor air quality in different locations of Amman (https://en.jordanenv.com/).

Airborne pollutants like fine particulate matter and airborne heavy metals can trigger inflammation in the body, including the nervous system. Chronic inflammation may lead to neuroinflammation, which is associated with various neurological disorders. Long-term exposure to air pollutants has been associated with deficits in cognitive function. Prenatal exposure to air pollution, especially in areas with high pollution levels, has been linked to adverse neuro-developmental outcomes in children. This can include behavioral problems, developmental delays, and a higher risk of conditions like autism and attention deficit hyperactivity disorder. There is also growing evidence that air pollution may be associated with mood disorders such as depression and anxiety.

Excess carbon dioxide in the air dissolves in seawater, leading to ocean acidification that can harm marine organisms with calcium carbonate shells or skeletons, including corals, mollusks, and some types of plankton. Excess nitrogen compounds can lead to the proliferation of harmful algal blooms, which can produce toxins that harm marine life, including fish and shellfish. These toxins can also pose risks to human health when seafood is consumed. Airborne micro plastics and other pollutants can find their way into the oceans, contributing to the growing problem of marine debris.

In conclusion, solutions to combat air pollution include increasing the scale of using renewable energy sources like solar and wind power. Promoting electric vehicles and expanding charging infrastructure can decrease emissions from transportation. Promoting vehicle pooling, biking and walking can further decrease emissions. Encourage sustainable farming and precision agriculture practices that reduce ammonia emissions from fertilisers and livestock. Implement urban planning that reduces congestion, encourages clean public transportation, and enhances air quality. Increase green spaces in cities with less heat islands and protect forests that can help in absorbing pollutants, providing cleaner air and thus better health for all biodiversity.

Ayoub Abu Dayyeh, The writer is an energy and green buildings consultant.

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Climate’s ‘Catch-22’: Cutting pollution heats up the planet

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Climate’s ‘Catch-22’: Cutting pollution heats up the planet is a conclusion reached by scientists after reviewing the results of China’s decade-long “war on pollution.”

That’s the unpalatable conclusion reached by scientists poring over the results of China’s decade-long and highly effective “war on pollution”, according to six leading climate experts.

The drive to banish pollution, caused mainly by sulphur dioxide (SO2) spewed from coal plants, has cut SO2 emissions by close to 90% and saved hundreds of thousands of lives, Chinese official data and health studies show.

 

Yet stripped of its toxic shield, which scatters and reflects solar radiation, China’s average temperatures have gone up by 0.7 degrees Celsius since 2014, triggering fiercer heatwaves, according to a Reuters review of meteorological data and the scientists interviewed.

“It’s this Catch-22,” said Patricia Quinn, an atmospheric chemist at the U.S. National Oceanic and Atmospheric Administration (NOAA), speaking about cleaning up sulphur pollution globally. “We want to clean up our air for air quality purposes but, by doing that, we’re increasing warming.”

Other highly polluted parts of the world, such as India and the Middle East, would see similar jumps in warming if they follow China’s lead in cleaning the skies of sulphur dioxide and the polluting aerosols it forms, the experts warned.

“Aerosols are masking one-third of the heating of the planet,” said Paulo Artaxo, an environmental physicist and lead author of the chapter on short-lived climate pollutants in the most recent round of reports by the Intergovernmental Panel on Climate Change (IPCC), completed this year.

“If you implement technologies to reduce air pollution, this will accelerate – very significantly – global warming in the short term.”

The Chinese and Indian environment ministries didn’t immediately respond to requests for comment on the effects of pollution unmasking.

The link between reducing sulphur dioxide and warming was flagged by the IPCC in a 2021 report which concluded that, without the solar shield of SO2 pollution, the global average temperature would already have risen by 1.6 degrees Celsius above preindustrial levels.

That misses the world’s goal of limiting warming to 1.5C, beyond which scientists predict irreversible and catastrophic changes to the climate, according to the IPCC, which pegs the current level at 1.1C.

The Reuters review of the Chinese data provides the most detailed picture yet of how this phenomenon is playing out in the real world, drawing on previously unreported numbers on changes in temperatures and SO2 emissions over the past decade and corroborated by environmental scientists.

Reuters interviewed 12 scientists in total on the phenomenon of unmasking globally, including four who have acted as authors or reviewers of sections on air pollution in IPCC reports.

They said there was no suggestion among climate experts that the world should let-up on fighting air pollution, a clear and present danger that the World Health Organization says causes about 7 million premature deaths a year, mostly in poorer countries.

Instead they stressed the need for more aggressive action to cut emissions of climate-warming greenhouse gases, with reducing methane seen as one of the most promising paths to offset pollution unmasking in the short term.

XI BATTLES ‘AIRPOCALYPSE’

President Xi Jinping pledged to tackle pollution when he took power in 2012 following decades of coal-burning that had helped turn China into “the factory of the world”. The following year, as record smog in Beijing inspired “Airpocalypse” newspaper headlines, the government unveiled what scientists called China’s version of the U.S. Clean Air Act.

On March 5, 2014, a week after Xi went on a walkabout during another extreme bout of smog in the capital, the government officially declared a war on pollution at the National People’s Congress.

Under the new rules, power plants and steel mills were forced to switch to lower-sulphur coal. Hundreds of inefficient factories were shuttered, and vehicle fuel standards toughened up. While coal continues to be China’s largest power source, smokestack scrubbers now strip out most SO2 emissions.

China’s SO2 emissions had decreased from a 2006 peak of at nearly 26 million metric tons to 20.4 million tons in 2013 thanks to more gradual emissions restrictions. But with the war on pollution, those emissions had plummeted by about 87% to 2.7 million metric tons by 2021.

The drop in pollution was accompanied by a leap in warming – the nine years since 2014 have seen national average annual temperatures in China of 10.34C, up more than 0.7C compared with the 2001-2010 period, according to Reuters calculations based on yearly weather reports published by the China Meteorological Administration.

Scientific estimates vary as to how much of that rise comes from unmasking versus greenhouse gas emissions or natural climate variations like El Nino.

The impacts are more acute at a local level near the pollution source. Almost immediately, China saw big warming jumps from its unmasking of pollution near heavy industrial regions, according to climate scientist Yangyang Xu at Texas A&M University, who models the impact of aerosols on the climate.

Xu told Reuters he estimated that unmasking had caused temperatures near the cities of Chongqing and Wuhan, long known as China’s “furnaces”, to rise by almost 1C since sulphur emissions peaked in the mid-2000s.

During heatwaves, the unmasking effect can be even more pronounced. Laura Wilcox, a climate scientist who studies the effects of aerosols at Britain’s University of Reading, said a computer simulation showed that the rapid decline in SO2 in China could raise temperatures on extreme-heat days by as much as 2C.

“Those are big differences, especially for somewhere like China, where heat is already pretty dangerous,” she said.

Indeed, heatwaves in China have been particularly ferocious this year. A town in the northwestern region of Xinjiang saw temperatures of 52.2C (126F) in July, shattering the national temperature record of 50.3C set in 2015.

Beijing also experienced a record heatwave, with temperatures topping 35C (95F) for more than four weeks.

INDIA AND MIDDLE EAST

The effects of sulphur unmasking are most pronounced in developing countries, as the U.S. and most of Europe cleaned up their skies decades ago. While the heat rise from sulphur cleanup is strongest locally, the effects can be felt in far-distant regions. One 2021 study co-authored by Xu found that a decrease in European aerosol emissions since the 1980s may have shifted weather patterns in Northern China.

In India, sulphur pollution is still rising, roughly doubling in the last two decades, according to calculations by NOAA researchers based on figures from the U.S.-funded Community Emissions Data System.

In 2020, when that pollution plummeted due to COVID lockdowns, ground temperatures in India were the eighth warmest on record, 0.29 C higher than the 1981-2010 average, despite the cooling effects of the La Nina climate pattern, according to the India Meteorological Department.

India aims for an air cleanup like China’s, and in 2019 launched its National Clean Air Programme to reduce pollution by 40% in more than 100 cities by 2026.

Once polluted regions in India or the Middle East improve their air quality by abandoning fossil fuels and transitioning to green energy sources, they too will lose their shield of sulphates, scientists said.

“You stop your anthropogenic activities for a brief moment of time and the atmosphere cleans up very, very quickly and the temperatures jump instantaneously,” added Sergey Osipov, a climate modeller at the King Abdullah University of Science and Technology in Saudi Arabia.

OFFSETTING WITH METHANE?

As the implications of the pollution unmasking become more apparent, experts are casting around for methods to counter the associated warming.

One proposal called “solar radiation management” envisions deliberately injecting sulphur aerosols into the atmosphere to cool temperatures. But many scientists worry that the approach could unleash unintended consequences.

A more mainstream plan is to curb methane emissions. This is seen as the quickest way to tame global temperatures because the effects of the gas in the atmosphere last only a decade or so, so cutting emissions now would deliver results within a decade. Carbon dioxide, by comparison, persists for centuries.

As of 2019, methane had caused about 0.5C in warming compared with preindustrial levels, according to IPCC figures.

While more than 100 countries have pledged to reduce methane emissions by 30% by the end of the decade, few have gone further than drawing up “action plans” and “pathways” to cuts. China – the world’s biggest emitter – has yet to publish its plan.

By targeting methane, the world could mitigate the warming effect of the reduction in pollution and potentially avert catastrophic consequences, said Michael Diamond, an atmospheric scientist at Florida State University.

“This doesn’t doom us to going above 1.5 degrees Celsius if we clean up the air.”

Reporting by Jake Spring in Sao Paulo and David Stanway in Singapore; Additional reporting by Sakshi Dayal in New Delhi; Editing by Katy Daigle and Pravin Char

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